Opens in a new tab
Clear, accurate chemistry definitions
1,500+ terms6 topics118-element periodic table
General Chemistry

Double Bond

Definition and meaning of Double Bond in chemistry.
A double bond is a strong connection between two atoms. It forms when the two atoms share two pairs of electrons. This means they share four electrons in total to stick together. This type of bond is very common in organic molecules.

In more detail

A double bond has two distinct and different parts. The first part is called a sigma bond. This forms when electron clouds overlap head-on between the atoms.

The second part is called a pi bond. This forms when p orbitals overlap sideways above and below the atoms. You can think of p orbitals as dumbbell-shaped clouds of electrons.

The pi bond locks the atoms into a flat shape. Breaking this sideways connection takes a large amount of energy. Because of this, atoms cannot spin freely around a double bond.

This fixed shape creates different chemical structures called isomers. Students often think a double bond equals two identical single bonds. This idea is a very common student misconception.

The sigma and pi bonds have completely different shapes and strengths. The sigma bond is actually much stronger than the pi bond. A double bond is shorter and stronger than a single bond.

It pulls the two bonded atoms closer together. But it is weaker than a carbon triple bond. The exposed electrons in the pi bond make the molecule reactive.

Other chemicals can attack these outside electrons to form new bonds. This chemical process is known as an addition reaction. Plant oils have many carbon double bonds in their long chains. These rigid bonds keep the oils liquid at room temperature.

Key facts

Field
General Chemistry
Composition
1 sigma bond plus 1 pi bond
Shared electrons
4 electrons total (2 pairs)
Bond order
2
Reactivity
Pi electrons make them targets for addition reactions
Classic example
Ethylene, C2H4
Example
Ethylene gas has a classic carbon-carbon double bond. Its chemical formula is written as C2H4. Each carbon shares four electrons with the other carbon atom. The carbon atoms also connect to two hydrogen atoms each. The pi bond prevents the two carbon atoms from twisting. This keeps all six atoms completely flat in one plane.

Frequently asked questions

Why can't atoms rotate freely around a double bond?

Rotation would force the sideways pi bond to break. This requires too much energy, so the atoms stay locked in place.

Is a double bond twice as strong as a single bond?

No. The pi bond is weaker than the sigma bond. The total strength is less than two single bonds combined.

How does a double bond change the shape of a molecule?

It creates a rigid flat area in the molecule. The atoms connected directly to the double bond must stay in the same plane.

Related terms