Opens in a new tab
Clear, accurate chemistry definitions
1,500+ terms6 topics118-element periodic table
General Chemistry

Lewis Base

Definition and meaning of Lewis Base in chemistry.
A Lewis base is any chemical substance that can donate a pair of nonbonding electrons to another chemical. This action forms a specific connection called a coordinate covalent bond. This broad definition expands the concept of a base far beyond just making hydroxide ions.

In more detail

Proposed by Gilbert N. Lewis, this modern theory focuses entirely on the movement of electron pairs. Older traditional theories only define bases by their ability to accept hydrogen protons or release hydroxide. For a molecule or ion to act as a Lewis base, it needs a very specific feature.

It absolutely must have at least one lone pair of electrons readily available for donation. When a Lewis base donates this pair to an electron-hungry species, they instantly link together. The electron-hungry partner receiving the pair is always known as a Lewis acid.

Together, the newly combined chemical product is called a Lewis acid-base adduct. This concept is incredibly powerful because it explains many complex reactions in coordination chemistry. It perfectly describes how various ligands bind to transition metal ions to form colorful complexes.

The older Brønsted-Lowry theory completely fails to explain these specific metal interactions because no protons actually move. A common student misconception is thinking a molecule can only follow one specific base theory. Many common chemicals act as both Brønsted-Lowry bases and Lewis bases depending on the exact reaction. However, the Lewis definition is much broader and covers a much wider variety of chemical reactions.

Key facts

Field
General Chemistry
Key Action
Donates an electron pair
Requirement
Must have a lone pair of electrons
Product formed
Lewis acid-base adduct
Bond type created
Coordinate covalent bond
Example
Ammonia (NH3) acts as a classic Lewis base when it reacts with boron trifluoride (BF3). The central nitrogen atom in ammonia has one nonbonding lone pair of electrons. Nitrogen gladly donates this lone pair to the empty orbital on the electron-deficient boron atom. This donation forms a strong coordinate covalent bond and creates a stable adduct molecule.

Frequently asked questions

Can a molecule be a Lewis base without being a Brønsted-Lowry base?

Yes, many molecules can donate an electron pair without ever accepting a hydrogen proton. Carbon monoxide is a great example because it binds to metals but mostly ignores protons.

Are all Brønsted-Lowry bases also Lewis bases?

Yes, almost all traditional Brønsted-Lowry bases contain at least one lone pair of electrons. They actually use that exact same lone pair to grab the incoming hydrogen proton.

What is the difference between a covalent bond and a coordinate covalent bond?

In a normal covalent bond, each atom donates one electron to make the shared pair. In a coordinate covalent bond, the Lewis base donates both electrons to make the pair.

Related terms