Opens in a new tab
Clear, accurate chemistry definitions
1,500+ terms6 topics118-element periodic table
Inorganic Chemistry

Magnesium Oxide

Definition and meaning of Magnesium Oxide in chemistry.
Magnesium oxide is an ionic chemical compound composed of magnesium cations and oxide anions. The elements combine in a strict one to one ratio. It exists as a bright white solid powder at room temperature. It is well known for its extremely high melting point and thermal stability.
Molecular structure diagram of Magnesium Oxide

In more detail

Magnesium oxide forms rapidly when pure magnesium metal burns in the presence of oxygen gas. This violent combustion produces a blinding white light and leaves behind a white powder. The compound consists of magnesium ions with a positive two charge and oxygen ions with a negative two charge.

These oppositely charged ions lock together in a repeating rock salt crystal structure. Very strong electrostatic forces hold the rigid lattice together tightly. This strong ionic bonding explains why magnesium oxide melts at over two thousand eight hundred degrees Celsius.

Students sometimes incorrectly assume that all metal oxides dissolve easily in pure water. Magnesium oxide is actually mostly insoluble in water. It does react very slowly with liquid water to create a weak base called magnesium hydroxide.

Because of this chemical behavior, chemists classify magnesium oxide as a basic oxide. Engineers use this durable compound heavily in heavy industry as a refractory material. A refractory material retains its physical strength and chemical stability at incredibly high temperatures.

Factories use it to line the inside of hot industrial furnaces and steel making crucibles. It also acts as a safe, effective electrical insulator in high temperature heating cables.

Key facts

Chemical Formula
MgO
Field
Inorganic Chemistry
Melting Point
Approximately 2852 degrees Celsius
Crystal Structure
Rock salt repeating lattice
Solubility
Mostly insoluble in water
Industrial Use
High temperature refractory material
Example
A classic high school chemistry experiment involves burning a small strip of magnesium ribbon using a Bunsen burner. The bright flame converts the shiny metal and oxygen gas into a crumbly white ash. This remaining ash is solid magnesium oxide. The balanced chemical equation is 2Mg + O2 yields 2MgO.

Frequently asked questions

Is magnesium oxide highly soluble in water?

No, it is generally insoluble in water. It will slowly react with moisture over time to form a slightly soluble compound called magnesium hydroxide.

What is the oxidation state of magnesium in MgO?

The oxidation state of magnesium is positive two. The magnesium atom loses two outer electrons to form a stable Mg2+ cation.

Why does magnesium oxide have such a high melting point?

It contains double charged ions packed into a tight crystal lattice. It takes massive amounts of thermal energy to break these strong ionic bonds.

Related terms

Sources & references